Water flowing through a tube conducts heat away much more effectively than steam due to its higher specific heat capacity. This means that tubes carrying water have a metal temperature much closer to the fluid passing through it.
Where superheat temperatures upto 455oC are in use then the use of mild steel is not a problem, for superheat temperatures above this then alloys of chrome molybdenum steels are used (upto 560oC), difficulties in welding means that there use is restricted to only within the highest temperature zone and a transition piece fitted to connect to remaining mild steel tubing.
Superheat temperature control is therefor fitted to ensure superheat temperature does not exceed design limits.
The balance line prevents any tendency for the control unit to steam under conditions of low feed flow say due to sudden load change or especially when flashing ( several of these have been burnt out due to incorrect flashing procedure)
The control unit operates the linkages via a control arm, if the superheat is too high then gasses are diverted to flow over the control unit and less gas now flows over the superheat bank.
The control arms and the dampers were very susceptible to damage caused by operating in the hot gas path. Also this control was very sensitive to excess air which can raise the superheat temperature by increasing the heat energy removed from the furnace.
Babcock and wilcock selectable superheat
This design gave a wide range of temperature control, it operated in a similar manner to the Foster Wheeler ESD II. The gas path is separated by a baffle which has flaps located above the tubes operation of which can determine the superheat temperature, as the superheater only extends across one path it is made out of 'W' rather than 'U' tubes.
This design suffered from similar problems to the ESD II with regard to flaps and flap linkages susceptibility to corrosion.
The superheat temperature was regulated by changing the position of lit burners within the boiler, shutting off burners in the main furnace and replacing them with flames in the wing furnace had the effect of reducing the superheat temperature as the gasses are cooler when the reach the superheater bank. In this way the superheat temperature could be varied by 60oC.
The advantage of this system was the superheat temperature could be maintained over a wide variation of load. To prevent reversal of flow in the intermediate generating bank a baffle plate is fitted in the water drum which allows the first two rows of the bank to be isolate from the rest and to be supplied by their own two downcomers.
As air is a relatively poor cooling medium large attemperators are required allied to increased FD fan output required to overcome frictional resistance losses. There is an overall increase in weight, size and initial cost which led to the system being superseded by the regulated gas flow method and then by water or spray cooled attemperation
Superheat control is achieved by diverting a proportion of the steam through the simple tubular heat exchanger attemperator
Shut off valves have to be fitted to the attemperator as in the event of tube leakage the boiler will empty in to the attemperator as it is at a slightly higher pressure due to frictional losses in the superheater.
The spray valves work in series with one reaching its maximum capacity before the second comes into use, the control system takes as its measured value both the outlet temperature and either steam or air flow (load). The spray valves are often designed to be of the air to open variety so in the event of air failure they will fail safe open.
Methods of regulating superheat temperature
a, By regulating the gas flow over the superheater by means of dampers
FW ESD II

b, By use of multi furnace boilers
Babcock and wilcock Controlled superheat)
Difficulty was encountered in maintaining the correct air/fuel ratio during differential firing of the two furnaces.
During flashing only the wing furnace is used to give better protection for the superheater
c,Use of air cooled attemperators
Air cooling effect of the double casing is lost in this arrangement so additional insulation must be fitted to ensure that the casing temperature does not exceed safe handling limits.
d, Use of separately fired superheater
In very rare use, normally limited to tank boilers
e, Use of boiler water attemperator (external mounting)

e, Water cooled attemperator (internal)


g, Water spray attemperation
This the most common form of attemperation in use, it consists of two spray nozzles which spray feed water into the steam as it passes from the primary to secondary superheaters. The water receives heat from the steam and thereby reduces the superheat of the steam. To prevent thermal shocking of the transfer pipe, a thin flexible inner tube is fitted. 